Metal-Catalyzed Postpolymerization Strategies for Polar Group Incorporation into Polyolefins Containing C–C, C?C, and Aromatic Rings

نویسندگان

چکیده

Polymeric materials bearing polar groups constitute a class of macromolecules with interest in number uses. Because the direct synthesis employing polymerization strategies from monomers is very often precluded by catalyst poisoning or uncontrolled side reactions, alternative postpolymerization route consisting modifying previously prepared polymer continuously progressing. However, such posteriori modification depends on existence potential reaction sites polymer. this, polyolefins are most challenging substrates to work and, among them, saturated ones. In this contribution, current state art metal-catalyzed and subsequent group incorporation provided.

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ژورنال

عنوان ژورنال: Macromolecules

سال: 2021

ISSN: ['0024-9297', '1520-5835']

DOI: https://doi.org/10.1021/acs.macromol.1c00374